Rapid hydrothermal synthesis of SrMo1−xWxO4 powders: Structure and luminescence characterization

- Intermediate compounds in the system SrMoO4-SrWO4 rapidly crystallised at 150 °C.
- Structural parameters of SrMo1−xWxO4 are unaffected by synthesis temperature.
- Rietveld and Raman's analyses revealed structural differences in SrMo1−xWxO4.
- Particle size and morphology of SrMo1−xWxO4 were affected by increasing W content.
- Green and blue emissions were attenuated in solid solutions with 25-50 mol% W.

Strontium molybdate, strontium tungstate particles and their solid solutions (SrMo1−xWxO4) with 0 ⩽ x ⩽ 1.0, were synthesised by means of a hydrothermal process. Crystallisation of SrMo1−xWxO4 particles took place rapidly using SrSO4 as the Sr precursor under hydrothermal conditions involving stirring (130 rpm) at 150 or 200 °C for 2 h. Structural analyses of the powders were conducted by XRD with Rietveld refinement and FT-Raman spectroscopy, and the particle shape was observed by FE-SEM. Lattice parameter measurements indicated a linear dependence of both “a0” and “c0” in the scheelite structured SrMo1−xWxO4 with a changing W content following Vegard's law. These analyses also provided evidence of the structural variation localised in the tetrahedral site as a result of the simultaneous incorporation of MoO4 and WO4 in the solid solutions formed in the compositional range of 9 ⩽ x ⩽ 60 mol%. The SrMo1−xWxO4 particles exhibited a predominantly euhedral shuttle-shaped morphology and particle sizes varying between 0.75 and 1.5 μm. The particle growth was affected by increasing the reaction temperature and the tungsten concentration. Photoluminescence analysis (PL) revealed a marked attenuation of the blue and green emissions preferentially for the powder containing 48.5 mol% of W, which makes it potentially useful for optoelectronic applications.

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