کد مقاله کد نشریه سال انتشار مقاله انگلیسی نسخه تمام متن
6464772 1362211 2016 6 صفحه PDF دانلود رایگان
عنوان انگلیسی مقاله ISI
Phase and morphological transformation stages during carbothermal reduction nitridation process: From coal gasification slag wastes to Ca-α-SiAlON powders
موضوعات مرتبط
مهندسی و علوم پایه مهندسی شیمی مهندسی شیمی (عمومی)
پیش نمایش صفحه اول مقاله
Phase and morphological transformation stages during carbothermal reduction nitridation process: From coal gasification slag wastes to Ca-α-SiAlON powders
چکیده انگلیسی


- Chemical structure of raw coal gasification slag is elucidated.
- Clear phase and morphological transformation stages are detected during CRN process.
- The mechanism of conversion reactions during CRN process is proposed.

Effective utilization of industrial solid wastes is of great benefit for environmental and economic needs. In order to clarify the theoretical issues and pave the way to synthesize high quality Ca-α-SiAlON powder from coal gasification slag by carbothermal reduction nitridation (CRN), in this study, the theoretical issues including the network structure of the slag as well as the phase and morphological transformation stages of raw slag during CRN process were comprehensively studied at different temperatures (1350, 1400, 1450 and 1500 °C). It was found that the CRN process was dominated by nitridation of the Ca-Si-Al-O glass component in slag. With the increase of processing temperature, spherical Ca-Si-Al-O particles were firstly nitrided into porous Ca-Si-Al-O-N spheres, plate-like O-SiAlON grains, and then nitrogen-rich SiAlONs (β-SiAlON, 15R polytypoid and α-SiAlON). At the end of CRN, Ca-α-SiAlON was found to be the only SiAlON phase presenting elongated prismatic morphology. In addition, high concentration Ca-α-SiAlON powder was obtained through a two-step purification process with a conversion rate as high as 45 wt%. The obtained results shed light on the preparation of Ca-α-SiAlON products from coal gasification slag and related wastes.

Carbothermal reduction nitridation process showing the phase and morphological transformation from coal gasification slag wastes to Ca-α-SiAlON powders.120

ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Advanced Powder Technology - Volume 27, Issue 5, September 2016, Pages 2232-2237
نویسندگان
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