کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
6469412 | 1423893 | 2017 | 10 صفحه PDF | دانلود رایگان |
- We synthesize two novel boron complexes based on imidazo[1,2-a]pyridine and four imidazo[1,2-a]pyridine-BODIPY dyads.
- DFT and TDDFT calculations have provided insight into interpreting the electronic properties.
- Luminescent emissions were investigated, and one imidazo[1,2-a]pyridine-BODIPY dyad 4a can be used as effective cell imaging regent.
Based on imidazo[1,2-a]pyridine derivatives, a series of mononuclear and binuclear fluorine-boron complexes 1a,b, 4a,b, and 5a,b have been designed and synthesized. X-ray crystal structures for single boron-core complexes 1b, 4a, 4b, and dual boron-core imidazo[1,2-a]pyridine-BODIPY dyad 5b were obtained, and intermolecular CHâ¯F interactions were observed in their solid state. High absorption coefficients, strong emissions, and high photostabilities have been demonstrated for these boron complexes. DFT and TD-DFT studies reveal efficient electronic interactions between the imidazo[1,2-a]pyridine moiety and BODIPY plane for dyads 4a,b, and 5a,b. Cell imaging of 4a was tested to show good cellular uptake ability.
219
Journal: Dyes and Pigments - Volume 142, July 2017, Pages 330-339