کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
6469517 | 1423974 | 2017 | 5 صفحه PDF | دانلود رایگان |
- A hybrid structure (NCH) composed of NiSe2 nanoparticles embedded in a CNT network is prepared.
- NCH is synthesized by scalable and low-cost spray drying and selenization.
- The NCH electrocatalyst delivers excellent HER performance and stability.
- The excellent HER behavior is due to the unique structure of the electrocatalyst.
For the first time, NiSe2 nanoparticles embedded in CNT networks have been synthesized via spray-drying followed by a selenization process. The NiSe2/CNTs hybrid (NCH) delivers superior electrocatalytic performance for HER. It has a low onset potential of ~ 159 mV and a cathode current density of 35.6 mA cmâ 2 at â 250 mV vs RHE; more importantly, the Tafel slope has a very low value of 29 mV decâ 1, which is comparable to a platinum (Pt) catalyst; in addition, it is stable even after 1000 cycles. The superior HER performance of NCH is attributed to its unique structure, which is composed of ultrathin NiSe2 nanoparticles homogenously embedded in highly conductive and porous CNT networks. This not only provides abundant HER active sites, but also guarantees robust contact between the NiSe2 nanoparticles and the CNT networks. The present study provides new insights into the large-scale and low-cost synthesis of a highly effective and stable NiSe2-based electrocatalyst which could be extended to large-scale production of other non-precious metal hybrid catalysts with low cost, high efficiency and excellent stability.
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Journal: Electrochemistry Communications - Volume 83, October 2017, Pages 51-55