کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
6469717 | 1423982 | 2017 | 4 صفحه PDF | دانلود رایگان |
• A new family of aromatic dicyanides was developed as the organic electrodes.
• 1,4-Dicyanobenzene (DCB) and 9.10-dicyanoanthracene (DCA) were studied.
• DCA exhibits more stable reduced states and superior electronic conductivity.
• DCA achieves reversible and step-by-step, two-electron process.
A new redox-active family of aromatic dicyanides was developed as organic electrodes in rechargeable batteries. The detailed electronic properties of two primary representatives of 1,4-dicyanobenzene (DCB) and 9,10-dicyanoanthracene (DCA) were studied. It is discovered that, as compared with DCB, the large aromatic π conjugation in DCA leads to better electron conductivity and more stable reduced states of DCA− and DCA2 −. The Li-ion batteries with DCA electrode are shown to have highly reversible operations.
Figure optionsDownload high-quality image (163 K)Download as PowerPoint slide
Journal: Electrochemistry Communications - Volume 75, February 2017, Pages 29–32