کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
6588399 | 1423232 | 2018 | 17 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
Cyclohexanone ammoximation over TS-1 catalyst without organic solvent in a microreaction system
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موضوعات مرتبط
مهندسی و علوم پایه
مهندسی شیمی
مهندسی شیمی (عمومی)
پیش نمایش صفحه اول مقاله
چکیده انگلیسی
We herein propose a highly efficient technology for the synthesis of cyclohexanone oxime, a key intermediate for the production of caprolactam. The classical cyclohexanone ammoximation over TS-1 catalyst needs t-butanol as the organic solvent to change the reaction system from liquid-liquid-solid to liquid-solid for much better reaction performances, which greatly increases the reactor size and the downstream separation cost. In this work, a solvent-free liquid-liquid-solid heterogeneous reaction was successfully implemented in a microreaction system containing two T-junction microreactors. The effects of temperature, pressure, residence time, concentrations of reactants and catalyst on the reaction performance were systematically investigated. This developed technology resulted in a 99.87% conversion of cyclohexanone and nearly 100% selectivity to cyclohexanone oxime within 3â¯min. These results indicate that the new process could provide a more environmental friendly and economic approach to caprolactam industry.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Chemical Engineering Science - Volume 187, 21 September 2018, Pages 60-66
Journal: Chemical Engineering Science - Volume 187, 21 September 2018, Pages 60-66
نویسندگان
Yunpeng Hu, Chen Dong, Tao Wang, Guangsheng Luo,