کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
6588504 | 1423235 | 2018 | 7 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
Constituent solubility and dissolution in a CuCl-HCl-H2O ternary system
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موضوعات مرتبط
مهندسی و علوم پایه
مهندسی شیمی
مهندسی شیمی (عمومی)
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چکیده انگلیسی
The copper-chlorine (Cu-Cl) cycle has significantly lower temperature requirements than most other cycles of thermochemical hydrogen production. The cycle involves multiple steps which include multiphase transport processes. Thermodynamic equilibrium of ternary mixtures in the Cu-Cl cycle have important effects on the transport processes. A ternary system consisting of cuprous chloride (CuCl), hydrochloric acid (HCl) and water exists in different variations of the Cu-Cl cycle. In this paper, new correlations are developed for the solubility of the ternary system, which are essential to providing accurate boundary conditions for the transport processes. This paper examines these multi-constituent transport processes and the corresponding constituent solubilities. A new semi-empirical formulation is presented for the solubility of the ternary system. Results are given and discussed.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Chemical Engineering Science - Volume 184, 20 July 2018, Pages 209-215
Journal: Chemical Engineering Science - Volume 184, 20 July 2018, Pages 209-215
نویسندگان
Ofelia A. Jianu, Zhaolin Wang, Greg F. Naterer, Marc A. Rosen,