کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
6590693 | 456861 | 2015 | 7 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
Specific and nonspecific effects of biologically active inorganic salts on inclusion complex formation of cyclodextrins with aromatic carboxylic acids
ترجمه فارسی عنوان
اثرات خاص و غیر اختصاصی نمک های معدنی فعال بیولوژیک در شکل گیری ترکیبات پیچیدگی سیکلوکودکسترین ها با اسید کربوکاتیک معطر
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کلمات کلیدی
موضوعات مرتبط
مهندسی و علوم پایه
مهندسی شیمی
مهندسی شیمی (عمومی)
چکیده انگلیسی
Inclusion complex formation of α- and β-cyclodextrins with zwitterionic nicotinic and m-aminobenzoic acids in water and 0.2 M solutions of KCl, KBr, KH2PO4 and K2SO4 was studied by 1H NMR and UV-spectroscopy. We complemented the experiments with statistical mechanics calculations in the framework of the 3D-RISM approach to analyze the ion-binding between inorganic univalent anions and positively charged groups of the acids under study. It was detected that binding affinity of cyclodextrins to the acids is decreased in the presence of the salts. This is caused by specific and nonspecific action of the considered inorganic anions. The influence of the Clâ and SO42â was found to be nonspecific and insignificant. On the contrary, Brâ and H2PO4â ions can considerably affect the inclusion complex formation. Insertion of Brâ into the macrocyclic cavity and attraction between H2PO4â and the zwitterions are the main processes competing with cyclodextrin-acid binding. It has been demonstrated that the manifestation of the salt effects depends on the cyclodextrin cavity size, ionization state of the acid and other experimental conditions.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Chemical Engineering Science - Volume 122, 27 January 2015, Pages 97-103
Journal: Chemical Engineering Science - Volume 122, 27 January 2015, Pages 97-103
نویسندگان
Irina Terekhova, Ekaterina Chibunova, Roman Kumeev, Sergey Kruchinin, Marina Fedotova, MaÅgorzata KozbiaÅ, MaÅgorzata Wszelaka-Rylik, Pawel Gierycz,