کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
6592737 | 1423362 | 2018 | 22 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
Distinct synergetic effects in the ozone enhanced photocatalytic degradation of phenol and oxalic acid with Fe3Â +/TiO2 catalyst
دانلود مقاله + سفارش ترجمه
دانلود مقاله ISI انگلیسی
رایگان برای ایرانیان
کلمات کلیدی
موضوعات مرتبط
مهندسی و علوم پایه
مهندسی شیمی
مهندسی شیمی (عمومی)
پیش نمایش صفحه اول مقاله
چکیده انگلیسی
In this work, phenol and oxalic acid (OA) degradation in an ozone and photocatalysis integrated process was intensively conducted with Fe3Â +/TiO2 catalyst. The ferrioxalate complex formed between Fe3Â + and oxalate accelerated the removal of OA in the ozonation, photolysis and photocatalytic ozonation process, for its high reactivity with ozone and UV. Phenol was degraded in ozonation and photolysis with limited TOC removal rates, but much higher TOC removal was achieved in photocatalytic ozonation due to the generation of OH. The sequence of UV light and ozone in the sequential process also influences the TOC removal, and ozone is very powerful to oxidize intermediates catechol and hydroquinone to maleic acid. Fenton or photo-Fenton reactions only played a small part in Fe3Â +/TiO2 catalyzed processes, because Fe3Â + was greatly reduced but not regenerated in many cases. The synergetic effect was found to be highly related with the property of the target pollutants. Fe3Â +/TiO2 catalyzed system showed the highest ability to destroy organics, but the TiO2 catalyzed system showed little higher synergy.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Chinese Journal of Chemical Engineering - Volume 26, Issue 7, July 2018, Pages 1528-1535
Journal: Chinese Journal of Chemical Engineering - Volume 26, Issue 7, July 2018, Pages 1528-1535
نویسندگان
Yongbing Xie, Yingying Chen, Jin Yang, Chenming Liu, He Zhao, Hongbin Cao,