کد مقاله کد نشریه سال انتشار مقاله انگلیسی نسخه تمام متن
6593017 1423365 2018 22 صفحه PDF دانلود رایگان
عنوان انگلیسی مقاله ISI
17α-Ethinylestradiol removal from water by magnetic ion exchange resin
موضوعات مرتبط
مهندسی و علوم پایه مهندسی شیمی مهندسی شیمی (عمومی)
پیش نمایش صفحه اول مقاله
17α-Ethinylestradiol removal from water by magnetic ion exchange resin
چکیده انگلیسی
Magnetic ion exchange (MIEX) resins have received considerable attention in drinking water treatment due to their fast and efficient removal of dissolved organic carbon (DOC). Two types of mechanisms, i.e., ion exchange, reversible and irreversible adsorption, may occur during pollutants removal by MIEX. This work examined the removal mechanism of 17α-Ethinylestradiol (EE2) by MIEX. As one of typical estrogen micro-pollutants, EE2 existed as neutral molecule in natural water, and its charge density was close to zero [(0.00000219 ± 0.00000015) meq·(μg EE2)− 1] based on the potentiometric titration method. However, the removal of EE2 by MIEX was much higher than that of other micro-pollutants previously reported. Multi-cycle adsorption-regeneration experiments and ion exchange stoichiometry analysis were conducted to elucidate the removal mechanism of EE2 by MIEX resin. The results suggested that the main removal mechanism of EE2 by MIEX was ion exchange instead of reversible micro-pore adsorption. The experimental analysis based on Donnan theory indicated that the internal micro-environment of resin beads was alkaline, in the alkaline environment EE2 would be ionized into negatively charged groups. As a result, ion exchange reaction occurred inside the pore of MIEX resin, and the removal process of EE2 by MIEX was dominated by the ion exchange reaction.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Chinese Journal of Chemical Engineering - Volume 26, Issue 4, April 2018, Pages 864-869
نویسندگان
, , , , , , ,