کد مقاله کد نشریه سال انتشار مقاله انگلیسی نسخه تمام متن
6593150 1423367 2018 32 صفحه PDF دانلود رایگان
عنوان انگلیسی مقاله ISI
Characteristics of oil shale pyrolysis in a two-stage fluidized bed
ترجمه فارسی عنوان
مشخصات پیرولیز شیله نفتی در یک تخت مایع دو مرحله ای
کلمات کلیدی
موضوعات مرتبط
مهندسی و علوم پایه مهندسی شیمی مهندسی شیمی (عمومی)
چکیده انگلیسی
Rapid pyrolysis of oil shale coupled with in-situ upgrading of pyrolysis volatiles over oil shale char was studied in a laboratory two-stage fluidized bed (TSFB) to clarify the shale oil yield and quality and their variations with operating conditions. Rapid pyrolysis of oil shale in fluidized bed (FB) obtained shale oil yield higher than the Fischer Assay oil yield at temperatures of 500-600 °C. The highest yield was 12.7 wt% at 500 °C and was about 1.3 times of the Fischer Assay oil yield. The heavy fraction (boiling point > 350 °C) in shale oil at all temperatures from rapid pyrolysis was above 50%. Adding an upper FB of secondary cracking over oil shale char caused the loss of shale oil but improved its quality. Heavy fraction yield decreased significantly and almost disappeared at temperatures above 550 °C, while the corresponding light fraction (boiling point < 350 °C) yield dramatically increased. In terms of achieving high light fraction yield, the optimal pyrolysis and also secondary cracking temperatures in TSFB were 600 °C, at which the shale oil yield decreased by 17.74% but its light fraction yield of 7.07 wt% increased by 86.11% in comparison with FB pyrolysis. The light fraction yield was higher than that of Fischer Assay at all cases in TSFB. Thus, a rapid pyrolysis of oil shale combined with volatile upgrading was important for producing high-quality shale oil with high yield as well.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Chinese Journal of Chemical Engineering - Volume 26, Issue 2, February 2018, Pages 407-414
نویسندگان
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