کد مقاله کد نشریه سال انتشار مقاله انگلیسی نسخه تمام متن
6593260 1423369 2017 19 صفحه PDF دانلود رایگان
عنوان انگلیسی مقاله ISI
Catalytic performance of hybrid Pt@ZnO NRs on carbon fibers for methanol electro-oxidation
موضوعات مرتبط
مهندسی و علوم پایه مهندسی شیمی مهندسی شیمی (عمومی)
پیش نمایش صفحه اول مقاله
Catalytic performance of hybrid Pt@ZnO NRs on carbon fibers for methanol electro-oxidation
چکیده انگلیسی
A novel Pt@ZnO nanorod/carbon fiber (NR/CF) with hierarchical structure was prepared by atomic layer deposition combined with hydrothermal synthesis and magnetron sputtering (MS). The morphology of Pt changes from nanoparticle to nanorod bundle with controlled thickness of Pt between 10 and 50 nm. Significantly, with the increase of voltage from 0 to 0.6 V (vs. standard calomel electrode), the prompt photocurrent generated on ZnO NR/CF increases from 0.235 to 0.725 mA. Besides, the Pt@ZnO NR/CF exhibited higher electrochemical active surface area (ECSA) value, better methanol oxidation ability and CO tolerance than Pt@CF, which demonstrated the importance of the multifunctional ZnO support. As the thickness of Pt increasing from 10 to 50 nm, the ECSA values were improved proportionally, leading to the improvement of methanol oxidation ability. More importantly, UV radiation increased the density of peak current of Pt@ZnO NR/CF towards methanol oxidation by additional 42.4%, which may be due to the synergy catalysis of UV light and electricity.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Chinese Journal of Chemical Engineering - Volume 25, Issue 12, December 2017, Pages 1871-1876
نویسندگان
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