کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
6598245 | 1423878 | 2018 | 8 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
Gelation properties of terpyridine gluconic acid derivatives and their reversible stimuli-responsive white light emitting solution
ترجمه فارسی عنوان
خصوصیات ژل مشتقات تری گلیسیرید ترپیریدین و محلول اشعه ایکس سفید واکنش پذیر آنها
دانلود مقاله + سفارش ترجمه
دانلود مقاله ISI انگلیسی
رایگان برای ایرانیان
کلمات کلیدی
موضوعات مرتبط
مهندسی و علوم پایه
مهندسی شیمی
مهندسی شیمی (عمومی)
چکیده انگلیسی
Two gluconic acid derivatives C3 and C6 bearing a terpyridyl moiety were designed and synthesized. Thanks to the hydrophilic interaction from glucosyl moiety, C3 and C6 can dissolve in polar solvents and gel aromatic solvents with a critical gel concentration of weight 1.5%. The solution consisting of organic ligand C3 as sensitizer and Ln(III) ions as emitters can realize white light emission with thermo- and chemical stimuli-response properties in luminescence spectra. Further, the self-assemblies of C3 and C6 were examined by the combination of the theoretical calculations via hybrid density functional theory (DFT) with 1H nuclear magnetic resonance (1HNMR) and powder X-ray diffraction (PXRD) analysis. The study actually provides a reliable method for the formation of potential functional smart materials.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Dyes and Pigments - Volume 157, October 2018, Pages 64-71
Journal: Dyes and Pigments - Volume 157, October 2018, Pages 64-71
نویسندگان
Yuzhe Zhang, Hewei Yang, Shuo Guan, Zihui Liu, Longyuan Guo, Jianwei Xie, Jiabin Zhang, Nuonuo Zhang, Jian Song, Bao Zhang, Yaqing Feng,