کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
6600367 | 458925 | 2015 | 9 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
Improvement of the quadratic non-linear optical properties of pyrimidine chromophores by N-methylation and tungsten pentacarbonyl complexation
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کلمات کلیدی
موضوعات مرتبط
مهندسی و علوم پایه
مهندسی شیمی
مهندسی شیمی (عمومی)
پیش نمایش صفحه اول مقاله
چکیده انگلیسی
In this contribution, we report the synthesis of two series of compounds: 4-(arylvinyl)-1-methylpyrimidinium derivatives and tungsten pentacarbonyl complexes of 4-(arylvinyl)pyrimidines. Their second order non-linear properties, measured by Electric-Field Induced Second Harmonic generation (EFISH) method, and their photophysical behavior were thoroughly investigated and compared to the corresponding 4-(arylvinyl)pyrimidines. A strong enhancement of the NLO response was observed upon methylation or complexation by W(CO)5 of the pyrimidine ring. DFT theoretical calculations were performed to provide complementary insights on the structure-properties relationships in particular concerning the amplitude of the NLO response.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Dyes and Pigments - Volume 113, February 2015, Pages 562-570
Journal: Dyes and Pigments - Volume 113, February 2015, Pages 562-570
نویسندگان
Sylvain Achelle, Samia Kahlal, Alberto Barsella, Jean-Yves Saillard, Xiaoyang Che, Julien Vallet, Filip BureÅ¡, Bertrand Caro, Françoise Robin-le Guen,