کد مقاله کد نشریه سال انتشار مقاله انگلیسی نسخه تمام متن
6669836 1427285 2018 57 صفحه PDF دانلود رایگان
عنوان انگلیسی مقاله ISI
Study of catalytic hydrodeoxygenation performance for the Ni/KIT-6 catalysts
موضوعات مرتبط
مهندسی و علوم پایه مهندسی شیمی مهندسی شیمی (عمومی)
پیش نمایش صفحه اول مقاله
Study of catalytic hydrodeoxygenation performance for the Ni/KIT-6 catalysts
چکیده انگلیسی
Ni/KIT-6 catalysts loaded with different amounts of metallic Ni were prepared by impregnation method. The prepared catalysts and their precursors were investigated through wide- and low-angle XRD, TEM, BET, H2-TPR, and H2-TPD analyzes. The catalytic hydrodeoxygenation performance of the catalysts was evaluated using ethyl acetate as a model bio oil compound. Results indicate that the catalytic hydrodeoxygenation performance of the prepared catalysts was directly related to hydrogen storage properties, hydrogen desorption properties, dispersion of the active component Ni, and so on. The ethyl acetate conversion and ethane selectivity of 25 wt% Ni/KIT-6 catalyst were 100 and 96.8%, respectively, at 300 °C, which shows the best performance. The hydrodeoxygenation activity of ethyl acetate was higher than that of methyl acetate and isopropyl acetate because of the effect of molecular polarity and size. And, this reaction is a structure sensitive reaction.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Journal of Saudi Chemical Society - Volume 22, Issue 5, July 2018, Pages 614-627
نویسندگان
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