کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
6670122 | 465024 | 2016 | 9 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
Synthesis, characterisation, XRD, molecular modelling and potential antibacterial studies of Co(II), Ni(II), Cu(II), Zn(II), Cd(II) and Hg(II) complexes with bidentate azodye ligand
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موضوعات مرتبط
مهندسی و علوم پایه
مهندسی شیمی
مهندسی شیمی (عمومی)
پیش نمایش صفحه اول مقاله
چکیده انگلیسی
Six monomeric complexes of Co(II), Ni(II), Cu(II), Zn(II), Cd(II) and Hg(II) with one O N donor bidentate azodye ligand, 3 - (p-tolylazo) - 4 - hydroxyl - 5 - methoxybenzaldehyde (LH) (TAHMB) have been prepared. The complexes have been characterised by analytical, conductance, magnetic susceptibility, IR, electronic spectra, ESR, NMR, X-ray diffraction (Powder pattern) spectra and molecular modelling studies. The Co (II) and Ni (II) complexes are found to be octahedral, Cu(II) complex is distorted octahedral and a tetrahedral stereochemistry has been assigned to Zn(II), Cd(II) and Hg(II) complexes. The energy optimised structures Figure 3, Figure 4, Figure 5 are proposed using the semi empirical ZINDO/1 quantum mechanical calculations. The Ni(II) complex is found to possess an orthorhombic crystal system. The potential antibacterial studies of the ligand and some metal complexes with gram positive and gram negative bacteria have given encouraging results.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Journal of Saudi Chemical Society - Volume 20, Issue 6, November 2016, Pages 635-643
Journal: Journal of Saudi Chemical Society - Volume 20, Issue 6, November 2016, Pages 635-643
نویسندگان
Bipin Bihari Mahapatra, Ramani Ranjan Mishra, Ashish Kumar Sarangi,