کد مقاله کد نشریه سال انتشار مقاله انگلیسی نسخه تمام متن
6688433 501886 2015 6 صفحه PDF دانلود رایگان
عنوان انگلیسی مقاله ISI
Impact of potassium promoter on Cu-Fe based mixed alcohols synthesis catalyst
موضوعات مرتبط
مهندسی و علوم پایه مهندسی انرژی مهندسی انرژی و فناوری های برق
پیش نمایش صفحه اول مقاله
Impact of potassium promoter on Cu-Fe based mixed alcohols synthesis catalyst
چکیده انگلیسی
Impacts of K promoter on microstructures of a precipitated Cu-Fe based catalyst were studied by N2-physisorption (BET), X-ray photoelectron spectroscopy (XPS), X-ray diffractometer (XRD) and hydrogen temperature-programmed desorption/reduction (H2-TPD/TPR). Mixed alcohols synthesis (MAS) was carried out in a fixed-bed reactor. The results indicated that incorporation of K in the Cu-Fe based catalyst decreased the surface area of the particles, whereas promoted the immigration of bulky iron species to surface layers and strengthened the interaction of surface Fe-Cu. The increase of K concentration weakened the H2 chemisorption and restrained the reduction of both the Cu and Fe species. The catalytic activity and mixed alcohols selectivity increased accompanied with a gradually increasing K concentration, and reached the highest values as the amount of K increased to 0.5 wt.%. Subsequently, the MAS activity and selectivity C2+OH presented a decreasing trend. In addition, the increase of K concentration facilitated the formation of heavy hydrocarbons.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Applied Energy - Volume 138, 15 January 2015, Pages 584-589
نویسندگان
, , , , , ,