Ultrasound assisted in situ emulsion polymerization for polymer nanocomposite: A review

• This review covers an ultrasound assisted synthesis of polymer nanocomposites using in situ emulsion polymerization.
• This technique helps in preparation of stable and finely dispersed polymer nanocomposite.
• Recent developments in the preparation of core–shell polymer nanocomposites were reported.

This review covers an ultrasound assisted synthesis of polymer nanocomposites using in situ emulsion polymerization. First of all, surface modification of core nanoparticles with a coupling agent and surfactant has been employed for the synthesis of core–shell polymer nanocomposites. In addition to application of ultrasound for the synthesis of core–shell polymer nanocomposites, due to its influential efficiency, sonochemistry has been extensively used not only as an aid of dispersion for inorganic nanoparticles and organo-clay, but also acts as an initiator to enhance polymerization rate for synthesis of polymer nanocomposites. In situ emulsion polymerization of hydrophobic monomers, such as methyl methacrylate, butyl acrylate, aniline, vinyl monomers and styrene, using surfactant and water soluble initiator were carried out for a synthesis of core–shell polymer nanocomposite. This technique assists in preparation of stable and finely dispersed polymer nanocomposite with the loading of inorganic particles up to 5 wt.%. Recent developments in the preparation of core–shell polymer nanocomposites using an ultrasound assisted method with their physical characteristics such as morphology, thermal, and rheological properties and their potential engineering applications have been discussed in this review.