کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
687416 | 1460129 | 2008 | 11 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
Dehydration of tetrahydrofuran (THF) by pervaporation using crosslinked copolymer membranes
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کلمات کلیدی
موضوعات مرتبط
مهندسی و علوم پایه
مهندسی شیمی
تکنولوژی و شیمی فرآیندی
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چکیده انگلیسی
Tetrahydrofuran (THF) is an important volatile intermediate used in chemical industries and its separation from water is encountered in many application. Three different copolymers of acrylamide with increasing amount of 2-hydroxyethyl methacrylate (HEMA), i.e. PAMHEMA-1, -2 and -3 were synthesized and the crosslinked (gelled) copolymer membranes made from these sol copolymers were used for pervaporative dehydration of THF over the concentration range of 0-14 wt% water in feed. These extremely hydrophilic gel copolymer membranes were found to be highly water selective in both sorption and diffusion through the membranes. Water flux was found to decrease with increase in degree of crosslinking from PAMHEMA-1 to 3 copolymer membranes. Among the three membranes PAMHEMA-1 membrane showed very high water selectivity (216) and reasonable flux (570 gm/m2 h for 0.56 wt% of water in feed at 50 °C temperature). Water was also found to have a strong positive coupling effect on THF permeation. The membranes were found to show both sorption as well as diffusion selectivity for water.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Chemical Engineering and Processing: Process Intensification - Volume 47, Issues 9â10, September 2008, Pages 1620-1630
Journal: Chemical Engineering and Processing: Process Intensification - Volume 47, Issues 9â10, September 2008, Pages 1620-1630
نویسندگان
S. Ray, S.K. Ray,