On the predictions and limitations of the Becker-Döring model for reaction kinetics in micellar surfactant solutions

► Micellar reaction kinetics may be described by the Becker-Döring equations. ► This system information may be captured by a simplified continuum model. ► A micellar solution following dilution re-equilibrates over two distinct timescales. ► The continuum model agrees with experimental observations for this process. ► Re-equilibration occurs much faster in some cases exposing an alternative mechanism.