کد مقاله کد نشریه سال انتشار مقاله انگلیسی نسخه تمام متن
7138884 1462016 2018 19 صفحه PDF دانلود رایگان
عنوان انگلیسی مقاله ISI
TeSen - tool for determining thermometric parameters in ratiometric optical thermometry
موضوعات مرتبط
مهندسی و علوم پایه شیمی شیمی آنالیزی یا شیمی تجزیه
پیش نمایش صفحه اول مقاله
TeSen - tool for determining thermometric parameters in ratiometric optical thermometry
چکیده انگلیسی
This work presents the method and numerical program along with graphical user interface (GUI) for calculating the standard parameters necessary to evaluate luminescence ratiometric thermometers - the thermometric parameter Δ, absolute sensitivity Sa, and relative sensitivity Sr. Despite the high interest in temperature sensing materials, to the best of our knowledge, no such tool has been reported up to date. This is currently usually done by researchers using a trial and error method and is a rather laborious task, with high risk of errors. The undoubtful benefit of employing an optimization technique lies in the very fast and precise determination of the parameters employing different models. The thermometric parameters Δ, Sa and Sr are calculated based on the luminescence emission spectra measured over a certain temperature range. Using the TeSen tool the thermometric parameters Δ can be calculated based both on the peak maxima and integrated surface areas under the peaks. The tool also allows testing the ratio of multiple peaks, different peak ranges, and different temperature ranges in a very convenient way. In this work TeSen tool was used to study several new sensor materials, presenting new cases of single and dual center luminescent ratiometric theremometers.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Sensors and Actuators B: Chemical - Volume 273, 10 November 2018, Pages 696-702
نویسندگان
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