کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
7140844 | 1462030 | 2018 | 24 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
Highly sensitive naked eye detection of Iron (III) and H2O2 using poly-(tannic acid) (PTA) coated Au nanocomposite
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موضوعات مرتبط
مهندسی و علوم پایه
شیمی
شیمی آنالیزی یا شیمی تجزیه
پیش نمایش صفحه اول مقاله
![عکس صفحه اول مقاله: Highly sensitive naked eye detection of Iron (III) and H2O2 using poly-(tannic acid) (PTA) coated Au nanocomposite Highly sensitive naked eye detection of Iron (III) and H2O2 using poly-(tannic acid) (PTA) coated Au nanocomposite](/preview/png/7140844.png)
چکیده انگلیسی
In the present study, we present a room temperature-, one-pot method for the synthesis of functional poly (tannic acid) (PTA)-based core@shell nanocomposites (core@PTA). The addition of tannic acid (TA) to gold (Au) salt solutions at mildly alkaline pH induced reduction of the metal salts to Au nanoparticles (NPs) while TA was oxidized and self-polymerized before encapsulating the AuNPs to form Au@PTA. Through the use of coordination chemistry, the synthesized Au@PTA was utilized as a naked eye sensor for iron (III) ions and H2O2. In the presence of Fe3+, Au@PTA aggregated and resulted in visible color change, showing high selectivity towards Fe3+ with visual detection limit of 20â¯Î¼M. Extension of the approach is used to detect H2O2 with visual detection limit of 0.4â¯Î¼M. Observation of the UV-vis spectra after the addition of analytes for the two detection systems revealed an additional peak in the H2O2 detection system atâ¯â¼â¯650â¯nm. This is due to the presence of “wire-like” oligomer structures in the H2O2 detection system as opposed to nanocomposite aggregation observed in the former system.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Sensors and Actuators B: Chemical - Volume 259, 15 April 2018, Pages 155-161
Journal: Sensors and Actuators B: Chemical - Volume 259, 15 April 2018, Pages 155-161
نویسندگان
Yan Fang, Jiajun Tan, Hyunjun Choi, Sierin Lim, Dong-Hwan Kim,