کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
7142313 | 1462053 | 2017 | 8 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
Molecularly imprinted electrodeposition o-aminothiophenol sensor for selective and sensitive determination of amantadine in animal-derived foods
دانلود مقاله + سفارش ترجمه
دانلود مقاله ISI انگلیسی
رایگان برای ایرانیان
موضوعات مرتبط
مهندسی و علوم پایه
شیمی
شیمی آنالیزی یا شیمی تجزیه
پیش نمایش صفحه اول مقاله
![عکس صفحه اول مقاله: Molecularly imprinted electrodeposition o-aminothiophenol sensor for selective and sensitive determination of amantadine in animal-derived foods Molecularly imprinted electrodeposition o-aminothiophenol sensor for selective and sensitive determination of amantadine in animal-derived foods](/preview/png/7142313.png)
چکیده انگلیسی
A novel molecularly imprinted electrochemical sensor was successfully fabricated for detection of amantadine (AM) residue in animal-derived foods. This molecularly imprinted film was prepared by electrodepositing o-aminothiophenol (o-AT) on a gold electrode surface by cyclic voltammetry (CV). A series of parameters, including template/monomer ratio, CV scanning cycle number, and immersion time, were optimized in detail for controlling the performance of this imprinted sensor. The fabricated sensor exhibited remarkable characteristics of high selectivity, sensitivity, and reproducibility, and long-term stability for AM detection. The imprinting factor for AM achieved to 2.33 and the selectivity factor for three structural analogues achieved to 6.20, 5.29 and 3.95. Under optimal experimental conditions, good linearity was observed between the current response and AM concentration, ranging from 4.0 Ã 10â7 mmol Lâ1 to 8.0 Ã 10â6 mmol Lâ1, with a detection limit of 3.06 Ã 10â9 mmol Lâ1 (S/N = 3). Satisfactory results for the measurement of real samples were also obtained using the proposed sensor, and were consistent with those derived from typical high-performance liquid chromatography-tandem mass spectrometry with a high correlation coefficient (R2 > 0.99). These results demonstrate that the proposed sensor could serve as a valuable tool for accurate and reliable detection of AM residue in animal-derived foods.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Sensors and Actuators B: Chemical - Volume 238, January 2017, Pages 32-39
Journal: Sensors and Actuators B: Chemical - Volume 238, January 2017, Pages 32-39
نویسندگان
Yaguang Yun, Mingfei Pan, Guozhen Fang, Yukun Yang, Ting Guo, Jiankang Deng, Bing Liu, Shuo Wang,