کد مقاله کد نشریه سال انتشار مقاله انگلیسی نسخه تمام متن
7143826 1462059 2016 6 صفحه PDF دانلود رایگان
عنوان انگلیسی مقاله ISI
Organic distributed feedback laser to monitor solvent extraction upon thermal annealing in solution-processed polymer films
ترجمه فارسی عنوان
لیزر بازخورد ایده آل برای بازرسی حلال پس از آنیلینگ حرارتی در فیلم های پلیمری پردازش شده با محلول توزیع شده است
کلمات کلیدی
راه حل، فیلم های پلیمری آنیلینگ حرارتی، آلی لیزر بازخورد توزیع شده،
موضوعات مرتبط
مهندسی و علوم پایه شیمی شیمی آنالیزی یا شیمی تجزیه
چکیده انگلیسی
Solution-processed polymer films are used in multiple technological applications. The presence of residual solvent in the film, as a consequence of the preparation method, affects the material properties, so films are typically subjected to post-deposition thermal annealing treatments aiming at its elimination. Monitoring the amount of solvent eliminated as a function of the annealing parameters is important to design a proper treatment to ensure complete solvent elimination, crucial to obtain reproducible and stable material properties and therefore, device performance. Here we demonstrate, for the first time to our knowledge, the use of an organic distributed feedback (DFB) laser to monitor with high precision the amount of solvent extracted from a spin-coated polymer film as a function of the thermal annealing time. The polymer film of interest, polystyrene in the present work, is doped with a small amount of a laser dye as to constitute the active layer of the laser device and deposited over a reusable DFB resonator. It is shown that solvent elimination translates into shifts in the DFB laser wavelength, as a consequence of changes in film thickness and refractive index. The proposed method is expected to be applicable to other types of annealing treatments, polymer-solvent combinations or film deposition methods, thus constituting a valuable tool to accurately control the quality and reproducibility of solution-processed polymer thin films.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Sensors and Actuators B: Chemical - Volume 232, September 2016, Pages 605-610
نویسندگان
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