کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
7147670 | 1462098 | 2014 | 7 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
A novel HBT-based Schiff base for colorimetric detection of aluminum: Synthesis, characterization, spectral and DFT computational studies
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کلمات کلیدی
موضوعات مرتبط
مهندسی و علوم پایه
شیمی
شیمی آنالیزی یا شیمی تجزیه
پیش نمایش صفحه اول مقاله
چکیده انگلیسی
A novel Schiff base L was easily synthesized by the condensation reaction of 2-aminophenol and p-hydroxyphenylbenzothiazole (p-HBT) and could be used for detection of aluminum in ethanol as well as in aqueous solution. Among the detected metal ions, only Al3+ ion can induce a significant enhancement in fluorescence intensity. The lowest detection limit and the dissociation constants Kd for Al3+ are determined to be 8.24Â ÃÂ 10â9Â M and 3.00Â ÃÂ 10â5Â M, respectively. In addition, the binding details of L-Al3+ complex were investigated by means of infrared spectra, 1H NMR titration and DFT computational studies, implying the fluorescence intensity enhanced by the inhibition of the ESIPT process in L, and further the formation of a large Ï-electron conjugation system.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Sensors and Actuators B: Chemical - Volume 192, 1 March 2014, Pages 386-392
Journal: Sensors and Actuators B: Chemical - Volume 192, 1 March 2014, Pages 386-392
نویسندگان
Shudi Liu, Liangwei Zhang, Wenyan Zan, Xiaojun Yao, Ying Yang, Xiang Liu,