کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
7149339 | 1462117 | 2012 | 9 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
A red-emission diketopyrrolopyrrole-based fluoride ion chemosensor with high contrast ratio working in a dual mode: Solvent-dependent ratiometric and “turn on” pathways
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کلمات کلیدی
موضوعات مرتبط
مهندسی و علوم پایه
شیمی
شیمی آنالیزی یا شیمی تجزیه
پیش نمایش صفحه اول مقاله
چکیده انگلیسی
A new diketopyrrolopyrrole derivative (DPP-4) with two triphenylamine groups was developed as red emission fluorescent sensor for fluoride ion. The fluorescent changes of DPP-4 interact with fluoride ion exhibiting obvious solvent-dependent properties. In acetone, ratiometric channel was activated upon addition of n-Bu4NF, and more than 50Â nm red shift from 590Â nm to 641Â nm was obtained and accompanied with emission color from orange to purple red. In acetonitrile, addition of fluoride caused 50-fold enhancement at 631Â nm in emission spectra which be defined as a “turn on” mode. Interestingly, using fluoride and HSO4â anions as two chemical inputs and absorption or fluorescence as output, compound DPP-4 is demonstrated to be a parallel double-INH logic gate in acetonitrile solutions.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Sensors and Actuators B: Chemical - Volume 173, October 2012, Pages 225-233
Journal: Sensors and Actuators B: Chemical - Volume 173, October 2012, Pages 225-233
نویسندگان
Yi Qu, Sanyin Qu, Lin Yang, Jianli Hua, Dahui Qu,