Interphase effect on the macroscopic elastic properties of non-bonded single-walled carbon nanotube composites

Compared to the small diameter of a carbon nanotube (CNT), the thickness of the CNT-matrix interphase in a CNT-composite is considerable. Hence, the interphase property can significantly influence the macroscopic properties of the composite. This paper applies an effective multi-scale method to explore such an interphase effect on the properties of nano-composites reinforced by single-walled CNTs. The method integrates the van der Waals (vdW) gap interphase, the dense interphase, and the randomly distributed wavy CNTs in a matrix to realize an accurate prediction of macroscopic properties with a nanoscopic resolution, by using a conventional finite element code commercially available. The study concluded that with the same volume fraction, increasing CNT waviness and diameter reduces the composite Young's modulus, and that ignoring either the vdW gap interphase or the dense interphase can lead to an erroneous characterization, and that both interphases can be ignored in some circumstances.