کد مقاله کد نشریه سال انتشار مقاله انگلیسی نسخه تمام متن
741824 894268 2006 6 صفحه PDF دانلود رایگان
عنوان انگلیسی مقاله ISI
Development of a parathion sensor based on molecularly imprinted nano-TiO2 self-assembled film electrode
موضوعات مرتبط
مهندسی و علوم پایه شیمی شیمی آنالیزی یا شیمی تجزیه
پیش نمایش صفحه اول مقاله
Development of a parathion sensor based on molecularly imprinted nano-TiO2 self-assembled film electrode
چکیده انگلیسی

Spontaneous formation of an ordered nano-TiO2/p-tert-butylcalix[4]arene hybrid thin film imprinted by parathion has been achieved by self-assembled technique, and a sensor based on the imprinted film has been constructed for the selective determination of parathion. A linear response to parathion in the concentration range of 5.0 × 10−8 to 1.0 × 10−5 M was observed with a good correlation coefficient (γ2 = 0.992). The linear regression equation was Ip (μA) = 0.202C (μM) + 0.797 and the detection limit of the sensor was 1.0 × 10−8 M (S/N = 3). The imprinted film sensor has been applied to the determination of parathion in spiked vegetable samples and the recoveries were varied from 93.3 to 103.3% at 0.3 and 2.0 μM.

ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Sensors and Actuators B: Chemical - Volume 117, Issue 1, 12 September 2006, Pages 166–171
نویسندگان
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