کد مقاله کد نشریه سال انتشار مقاله انگلیسی نسخه تمام متن
744322 894385 2008 6 صفحه PDF دانلود رایگان
عنوان انگلیسی مقاله ISI
Interdependence of ammonia and water sorption in polyacrylic acid layers
موضوعات مرتبط
مهندسی و علوم پایه شیمی شیمی آنالیزی یا شیمی تجزیه
پیش نمایش صفحه اول مقاله
Interdependence of ammonia and water sorption in polyacrylic acid layers
چکیده انگلیسی

Based on gravimetric measurements, a model describing the interdependence between the ammonia and water sorption in polyacrylic acid (PAA) is developed. The starting point is the fact that PAA-coated quartz microbalances (QMBs) show significant frequency shifts under exposure to ammonia and humidity. The response of the devices suggests that the mass increase under ammonia exposure, in humid air, is due to both the absorbed ammonia and the additionally absorbed water. At low humidity levels the ammonia changes the polymer matrix so that more water molecules can be absorbed. If the humidity is increased a glassy-to-rubbery state transition occurs that leads to a complex response of PAA-QMBs.

ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Sensors and Actuators B: Chemical - Volume 130, Issue 1, 14 March 2008, Pages 502–507
نویسندگان
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