کد مقاله کد نشریه سال انتشار مقاله انگلیسی نسخه تمام متن
746030 894439 2007 7 صفحه PDF دانلود رایگان
عنوان انگلیسی مقاله ISI
An electrochemical sensor for l-dopa based on oxovanadium-salen thin film electrode applied flow injection system
موضوعات مرتبط
مهندسی و علوم پایه شیمی شیمی آنالیزی یا شیمی تجزیه
پیش نمایش صفحه اول مقاله
An electrochemical sensor for l-dopa based on oxovanadium-salen thin film electrode applied flow injection system
چکیده انگلیسی

An oxovanadium-salen complex (N,N′-ethylene-bis(salicylideneiminato) oxovanadium) thin film deposited on a graphite–polyurethane electrode was investigated with regard to its potential use for detection of l-dopa in flow injection system. The oxovanadium(IV)/oxovanadium(V) redox couple of the modified electrode was found to mediate the l-dopa oxidation before its use in the FIA system. Experimental parameters, such as pH of the carrier solution, flow rate, sample volume injection and probable interferents were investigated. Under the optimized FIA conditions, the amperometric signal was linearly dependent on the l-dopa concentration over the range 1.0 × 10−6 to 1.0 × 10−4 mol L−1 (Ianodic μA) = 0.01 + 0.25 [l-dopa μmol L−1]) with a detection limit (S/N = 3) of 8.0 × 10−7 mol L−1 and a sampling frequency of 90 h−1 was achieved. For a concentration of 1.0 × 10−5 mol L−1l-dopa, the R.S.D. of nine consecutive measurements was 3.7%.

ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Sensors and Actuators B: Chemical - Volume 122, Issue 2, 26 March 2007, Pages 549–555
نویسندگان
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