Dissociative electron attachment to bromotrifluoromethane

- First comprehensive DEA study of CF3Br covering the energy range from 0 to 10 eV.
- Energy dependency of F−, FBr− and CF2Br− reported in this energy range (0-10 eV).
- 3-5 eV contributions assigned as two overlapping a1 and e symmetry shape resonances.
- Br− at 0 eV consistent with dissociation from the a1 σ*(CBr) anionic ground state.
- Br− and F− close to 8 eV in agreement with earlier vibrational scattering experiments.