کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
7640726 | 1494855 | 2018 | 24 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
Metsulfuron-methyl determination in environmental samples by solid surface fluorescence
ترجمه فارسی عنوان
تعیین متیسولفورون-متیل در نمونه های محیطی با استفاده از فلورسانس سطح جامد
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کلمات کلیدی
متیسولفورون متیل، علف کش، فلورسانس، استخراج فاز جامد،
موضوعات مرتبط
مهندسی و علوم پایه
شیمی
شیمی آنالیزی یا شیمی تجزیه
چکیده انگلیسی
A new environmental friendly methodology for metsulfuron-methyl quantification based on the fluorescent signal enhancement of rhodamine B dye has been developed. A cationic surfactant (cetyltrimethylammonium bromide, CTAB) and an anionic one (sodium dodecylsulfate) were employed to preconcentrate the herbicide using a coacervation phenomenon, in sodium borate buffer medium (pH 9.2). The coacervate phase was collected on a nylon membrane (0.45 μm) and the solid surface fluorescence signal was determined (λexc = 515 nm, λem = 565 nm). Experimental variables that influence on preconcentration step and fluorimetric sensitivity have been studied and optimized using response surface methodology. Under optimal working conditions, a LOD of 0.17 μg Lâ1 and a LOQ 0.53 μg Lâ1 was obtained. The zeroth order regression calibration was linear from 0.53 to 5.00 μg Lâ1. The method showed adequate sensitivity and selectivity, and was applied to the determination of trace amounts of metsulfuron-methyl in environmental water samples. The proposed methodology implies an alternative to traditional techniques for metsulfuron-methyl monitoring using an accessible instrument in control laboratories, representing a contribution in the toxicological and environmental areas for the monitoring of MSM in environmental samples, in agreement with the Green Chemistry.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Microchemical Journal - Volume 139, June 2018, Pages 150-154
Journal: Microchemical Journal - Volume 139, June 2018, Pages 150-154
نویسندگان
Magdalena Alesso, César A. Almeida, MarÃa C. Talio, Liliana P. Fernández,