Three new organic-inorganic hybrid di-copper-complex substituted monovacant phosphotungstates: Hydrothermal syntheses, structures and properties

Three new organic-inorganic hybrid di-copper-complex substituted monovacant polyoxotungstates have been hydrothermally prepared. Notably, 1-3 are all containing di-copper-complex substituted phosphotungstate subunits as well as different pendant copper cations and showing discrete, dimmer and 1D chain structures, respectively. Furthermore, the magnetic property of 1 has been investigated.199