کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
7748812 | 1498904 | 2017 | 16 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
Copper(II) complex derived from axial chiral heterocyclic spiro ligand: Crystal structure, characterization and SOD activity
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کلمات کلیدی
موضوعات مرتبط
مهندسی و علوم پایه
شیمی
شیمی معدنی
پیش نمایش صفحه اول مقاله
![عکس صفحه اول مقاله: Copper(II) complex derived from axial chiral heterocyclic spiro ligand: Crystal structure, characterization and SOD activity Copper(II) complex derived from axial chiral heterocyclic spiro ligand: Crystal structure, characterization and SOD activity](/preview/png/7748812.png)
چکیده انگلیسی
A new Cu(II) coordination polymer (1) constructed from an axially chiral heterocyclic spiro ligand, 2,4,8,10-tetraoxaspiro[5,5]undecane-3,9-dicarboxylic acid (H2L) and 1,3-bis(4-pyridyl)propane (bpp), has been prepared and characterized. Structural analysis shows that 1 features a 2D undulated layer of rhombic meshes with (4, 4) topology. Interestingly, a 1D wave-like water tape formed by the cyclic centrosymmetric chairlike octamer water clusters (H2O)8 are observed between the 2D sheets. Furthermore, the experimental data and computational studies of superoxide dismutase (SOD) activity of H2L and 1 were investigated.106
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Inorganic Chemistry Communications - Volume 86, December 2017, Pages 218-222
Journal: Inorganic Chemistry Communications - Volume 86, December 2017, Pages 218-222
نویسندگان
Yi-Fan Kang, Xiqiang Liang, Xiao Wang, Tiantian Si, Yitong Chen, Jianhua Zhang, Jing Zhao,