pH-dependent assembly of 1D-2D structures based on both {V10O28} and [NiMo6O24H6]4 − units: Synthesis, structure and magnetic properties

Two novel complexes consisting of both {V10O28} and [NiMo6O24H6]4 − units arise from a pH-dependent self-assembly process, in which both {V10O28} and [NiMo6O24H6]4 − anions could be bridged by Na+ ions to form the 1D chain-like and 2D layer structures under lower pH value.