Hydrothermal syntheses and characterization of a series of lead(II) inorganic-organic hybrid frameworks tuned by reaction temperature and inclusion of halide anions

A series of novel lead(II) inorganic-organic hybrid frameworks have been isolated under hydrothermal conditions. The variable lead(II) geometries and coordination numbers together with flexible coordination modes of de-protonated L2 − ligand also reveal great potential in the rational design and deliberate construction of those novel inorganic-organic hybrid materials.