Extruded tellurite glass optical fiber preforms

The extrusion behavior of tellurite glass in the supercooled liquid region was investigated. Good extrusion formability was observed under low strain rates at various temperatures in the glass transformation region investigated. Tube and holey fiber (HF) preforms were fabricated from tellurite glass billets using a laboratory press. In particular, the results for three-spoke HF design and round tube preforms with composition 75TeO2·20ZnO·5Na2O (TZN) are presented. The extruded preforms with precise geometrical features, an excellent surface quality and no crystallization were achieved in the temperatures range from 344 to 360 °C and at ram speeds ranging from 0.002 to 0.01 mm/s. Discrete shear bands were observed in the preforms, increasing in number and/or becoming better defined with increasing load and ram speed. Fewer shear bands were present when increasing the extrusion temperature from 344 to 360 °C. Thus, subsequent extrudates were successfully fabricated free of shear bands, providing good optical homogeneity that yielded solid and holey fibers that could provide much improved optical performance.