Effect of metal coating on machinability of high purity germanium using wire electrical discharge machining

This paper reports on the research of wire electrical discharge machining (WEDM) as a cutting process for n-type high purity germanium (HP Ge). WEDM requires sufficient electrical conductivity of the work piece for discharges to occur. Owing to the very high material resistivity of HP Ge (32.8 Ω cm), the electrical conduction is too low for WEDM to be efficient. To temporarily enhance the conduction, metals (aluminum and nickel) were deposited on the HP Ge on 1 or 2 sides with various thicknesses (1.0, 2.0, and 3.0 μm) using sputter deposition. This shortens the path of conduction between the HP Ge and the WEDM ground and also serves to trigger the discharges. Machining experiments were performed to determine the correlation between the slicing rate and locally enhanced HP Ge through various discharge energies (potential voltage: 150, 200, 250 and 300 V and capacitance: 1, 3.3, 5.5, 9.9 and 21.4 nF). From the results, the obtained maximum slicing rate is 7.7 mm2/min for Al coating (2 sides, 1.0 μm thickness) at high energy (300 V, 21.4 nF), which is improved as much as 27 times over uncoated HP Ge. The fastest cutting without creating subsurface microcracks was measured as 1.12 mm2/min performed at 150 V and 9.9 nF. Additional slicing experiments at reverse polarity (positive wire and negative work piece, uncommon polarity for WEDM) were performed at 150 V and various capacitances. The experiment proved that there were rectifying contacts at the metal coating surface. It was found that under identical EDM settings, a faster slicing rate also showed a reduction in kerf size due to less lateral discharge energy. Scanning electron microscopy (SEM), energy dispersive X-ray spectroscopy (EDS), and X-ray photoelectron spectroscopy (XPS) were used to investigate microcracks and to analyze surface impurities.