کد مقاله کد نشریه سال انتشار مقاله انگلیسی نسخه تمام متن
800282 1467175 2006 23 صفحه PDF دانلود رایگان
عنوان انگلیسی مقاله ISI
Modeling morphology evolution and mechanical behavior during thermo-mechanical processing of semi-crystalline polymers
موضوعات مرتبط
مهندسی و علوم پایه سایر رشته های مهندسی مهندسی مکانیک
پیش نمایش صفحه اول مقاله
Modeling morphology evolution and mechanical behavior during thermo-mechanical processing of semi-crystalline polymers
چکیده انگلیسی

A new model is proposed that combines statistical mechanics and thermodynamic aspects to characterize orientation development, nucleation and growth of crystallites, and chain entanglement slippage with interdependent relationships necessary to accurately correlate and in some cases predict the morphology and mechanical behavior of semi-crystalline polymers during various thermo-mechanical processes in the rubbery state, close to the glass transition temperature. Internal state variables (ISVs) that directly represent the underlying microstructure state are used to characterize polymer morphology and the resulting properties throughout deformation. The model uses fundamental thermodynamic coefficients for polyethylene terephthalate (PET) and is correlated to experimental data at various strain rates and temperatures just above the glass transition temperature. Experimental data are used that measure the stress, amorphous orientation, and crystallinity during uniaxial deformation of PET. The model is found to correlate well to these experimental data.

ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Journal of the Mechanics and Physics of Solids - Volume 54, Issue 3, March 2006, Pages 467–489
نویسندگان
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