A new type of magnetism-controllable Mn-based single-molecule magnet

The flexibility and diversity of organic chemistry have yielded many materials in which magnetism can be varied. However, most methods used for changing magnetism are inefficient or destructive to the magnetic material. Here we report high-performance magnetic control of a gas-responsive single-molecule magnet (SMM). The results exhibit that the magnetic properties of the SMM can be significantly changed according to the gas environment it is in and some of the magnetic states can be reversibly transformed or coexistent in the SMM through artificial control. More importantly, the single crystalline structure of the SMM is almost the same during the transformation process except for slight change of the lattice constant. Thus, this work opens up new insights into the stimuli-responsive magnetic materials which have great prospects for application in artificial design magnetic network and also highlight their potential as smart materials.