کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
8157778 | 1524873 | 2013 | 6 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
Clusters and ions in {TR6}X12R (T=Fe, Co, Ru, Os, Ir, R=Dy, Ho, Er, X=Br, I)-A magnetic study
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کلمات کلیدی
موضوعات مرتبط
مهندسی و علوم پایه
فیزیک و نجوم
فیزیک ماده چگال
پیش نمایش صفحه اول مقاله
چکیده انگلیسی
Eight cluster complex compounds with the composition {TR6}X12R (T=Fe, Co, Ru, Os, Ir, R=Dy, Ho, Er, X=Br, I) exhibiting the same crystal structure, {BSc6}Cl12Sc type, were investigated by magnetometry. A diversity of magnetic properties was recorded depending on chemical compositions. Long range spin order is suggested for {CoHo6}I12Ho, {FeHo6}I12Ho and {OsDy6}I12Dy below 40, 20 and 17Â K, respectively. The occurrence of 1-10% magnetic energy losses at lower temperatures with strong frequency dependence makes several of the compounds comparable with molecular magnets. Both the {TR6} cluster and the single R3+ ion contribute to out-of-phase susceptibility; these effects appear separately and can be investigated individually by employing an AC-magnetic field.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Journal of Magnetism and Magnetic Materials - Volume 347, December 2013, Pages 4-9
Journal: Journal of Magnetism and Magnetic Materials - Volume 347, December 2013, Pages 4-9
نویسندگان
Martin Valldor, Eva Meyer, Christian Rustige, Gerd Meyer,