Mechanical and thermal properties of phthalonitrile resin reinforced with silicon carbide particles

• SiC microparticles improve the mechanical properties of phthalonitrile resin.
• Excellent thermal stability achieved by adding SiC particles in phthalonitrile resin.
• Adding 20 wt.% of SiC microparticles increases the Tg by 38 °C.
• Silane coupling agent can enhance the adhesion and dispersion of particles/matrix.

A new type of composite based on phthalonitrile resin reinforced with silicon carbide (SiC) microparticles was prepared. For various weight ratios ranging between 0% and 20%, the effect of the micro-SiC particles on the mechanical and thermal properties has been studied. Results from thermal analysis revealed that the starting decomposition temperature and the residual weight were significantly improved upon adding the reinforcing phase. At the maximum micro-SiC loading, dynamic mechanical analysis (DMA) showed an important enhancement in both the storage modulus and glass transition temperature (Tg), reaching 3.1 GPa and 338 °C, respectively. The flexural strength and modulus as well as the microhardness were significantly enhanced by adding the microfillers. Tensile test revealed enhancements in the composites toughness upon adding the microparticles. Polarization optical microscope (POM) and scanning electron microscope (SEM) analysis confirmed that mechanical and thermal properties improvements are essentially attributed to the good dispersion and adhesion between the particles and the resin.

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