Synergism of carbon fiber and polyimide in polytetrafluoroethylene-based composites: Friction and wear behavior under sea water lubrication

Polytetrafluoroethylene-based (PTFE-based) composites reinforced simultaneously with carbon fiber (CF) and polyimide (PI) of different volume fractions were prepared. The microstructure and phase composition of as-prepared PTFE-based composites were analyzed by means of scanning electron microscopy (SEM) and X-ray diffraction (XRD). Besides, their friction and wear behavior under sea water lubrication was evaluated in relation to the synergistic effect between CF and PI using a ring-on-block test rig, and their worn surfaces were also analyzed using SEM. Results showed that the incorporation of PI induced loosening of the microstructure of PTFE but increased the wear resistance. Contrary to the above, the incorporation of CF led to increased compactness of PTFE, and the compactness as well as wear resistance of the PTFE-based composites increased with the increase of CF content. More importantly, the simultaneous incorporation of PI and CF at a proper volume fraction led to drastically reduced wear rate of PTFE under sea water lubrication. This implies that there exists synergistic friction-reducing and wear-resistant effect between PI and CF. As a result, the PTFE-based composite containing 5% PI (volume fraction) and 15% CF had the best wear resistance, showing promising application in ocean environment.

► The effect of PI and CF on the microstructure of PTFE was investigated.
► PI and CF had synergism on the improvement of tribological property of PTFE.
► PTFE-4 (with 5% PI and 15% CF) showed promising application in ocean environment.