Blends of carbon dioxide and HFCs as working fluids for the low-temperature circuit in cascade refrigerating systems

This paper describes an analysis on the performances of a cascade refrigeration cycle operated with blends of carbon dioxide (CO2, or R744) and hydrofluorocarbons (HFC) as the low-temperature working fluid. The aim of this work was to study the possibility of using carbon dioxide mixtures in those applications where temperatures below CO2 triple point (216.58 K) are needed. The analysis was carried out by developing a software based on the Carnahan-Starling-De Santis (CSD) equation of state (EoS) using binary interaction parameters derived from our experimental data. The properties of the investigated blends (R744/R125, R744/R41, R744/R32, R744/R23) were used to simulate the behavior of a cascade cycle using ammonia (R717) as the high-temperature-circuit working fluid and operating at evaporating temperatures down to −70 °C. The use of a suction-liquid heat exchanger on the low-temperature side of the circuit was also investigated. Results show that the R744 blends are an attractive option for the low-temperature circuit of cascade systems operating at temperatures approaching 200 K.