کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
9742845 | 1490469 | 2005 | 16 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
On the mechanical foundations of thermodynamics: The generalized Helmholtz theorem
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موضوعات مرتبط
مهندسی و علوم پایه
فیزیک و نجوم
فیزیک و نجوم (عمومی)
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چکیده انگلیسی
An elegant but seldom appreciated effort to provide a mechanical model of equilibrium thermodynamics dates back to the Helmholtz theorem (HT). According to this theorem, the thermodynamic relations hold mechanically (without probabilistic assumptions) in the case of one-dimensional monocyclic systems. Thanks to a discrete picture of the phase space, Boltzmann was able to apply the HT to multi-dimensional ergodic systems, suggesting that the thermodynamic relations we observe in macroscopic systems at equilibrium are a direct consequence of the microscopic laws of dynamics alone. Here I review Boltzmann's argument and show that, using the language of the modern ergodic theory, it can be safely re-expressed on a continuum phase space as a generalized Helmholtz theorem (GHT), which can be readily proved. Along the way the agreement between the Helmholtz-Boltzmann theory and that of P. Hertz (based on adiabatic invariance) is revealed. Both theories, in fact, lead to define the entropy as the logarithm of the phase-space volume enclosed by the constant energy hyper-surface (volume entropy).
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Studies in History and Philosophy of Science Part B: Studies in History and Philosophy of Modern Physics - Volume 36, Issue 2, June 2005, Pages 275-290
Journal: Studies in History and Philosophy of Science Part B: Studies in History and Philosophy of Modern Physics - Volume 36, Issue 2, June 2005, Pages 275-290
نویسندگان
Michele Campisi,