کد مقاله کد نشریه سال انتشار مقاله انگلیسی نسخه تمام متن
9746593 1492397 2005 6 صفحه PDF دانلود رایگان
عنوان انگلیسی مقاله ISI
Impulsional mode operation for a Paul ion trap
موضوعات مرتبط
مهندسی و علوم پایه شیمی شیمی آنالیزی یا شیمی تجزیه
پیش نمایش صفحه اول مقاله
Impulsional mode operation for a Paul ion trap
چکیده انگلیسی
The aim of this article is to provide some theoretical basis concerning the impulsional mode of a Paul ion trap using a periodic impulsional voltage of the form V0 cos (Ωt)/(1 − k cos (2 Ωt)) with k = 0.99. The performance characteristics of this impulsional mode is illustrated, and compared to the classical sinusoidal mode k = 0. Numerical computations allowed the determination of the fractional resolution m/Δm of the confined ions, in the first stability regions of both excitation voltage modes. An excellence resolution performance of the impulsional mode can be expected in the lower mass range of 1-2 u, by introducing the same uncertainties values for both operation modes in, machinery accuracy r0, stability of rf frequency Ω, the rf voltage amplitude V0→p and the accuracy of the modulation index parameter k.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: International Journal of Mass Spectrometry - Volume 247, Issues 1–3, 1 December 2005, Pages 61-66
نویسندگان
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