کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
9746673 | 1492402 | 2005 | 12 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
Gas-phase CS bond cleavage and crown opening versus nitrogen heterocycle loss from RuII complex ions with 1,4,7,10-tetrathiacyclododecane and bidentate diimines
دانلود مقاله + سفارش ترجمه
دانلود مقاله ISI انگلیسی
رایگان برای ایرانیان
موضوعات مرتبط
مهندسی و علوم پایه
شیمی
شیمی آنالیزی یا شیمی تجزیه
پیش نمایش صفحه اول مقاله
![عکس صفحه اول مقاله: Gas-phase CS bond cleavage and crown opening versus nitrogen heterocycle loss from RuII complex ions with 1,4,7,10-tetrathiacyclododecane and bidentate diimines Gas-phase CS bond cleavage and crown opening versus nitrogen heterocycle loss from RuII complex ions with 1,4,7,10-tetrathiacyclododecane and bidentate diimines](/preview/png/9746673.png)
چکیده انگلیسی
A new series of ruthenium(II) complexes with the general formula [RuII([12]aneS4)(NN)]X2, where NN are bidentate diimines, [12]aneS4 is 1,4,7,10-tetrathiacyclododecane, and X is Clâ or PF6â, were studied by electrospray mass spectrometry (ESMS). Thiacrown fragmentation and intact diimine loss are the two major types of gas-phase reactions observed. The diimine losses occur mainly from the ion pairs formed by the inner sphere cations with halogen anions and are more significant for the complexes with flexible cross-bridged diimines. The fragmentations occur predominantly without changes in the oxidation state of the metal centre.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: International Journal of Mass Spectrometry - Volume 243, Issue 3, 1 June 2005, Pages 257-268
Journal: International Journal of Mass Spectrometry - Volume 243, Issue 3, 1 June 2005, Pages 257-268
نویسندگان
Raul A. Izquierdo, Cristina M.F. Barros, Francisco M.L. Amado, M. Graça O. Santana-Marques, A.J. Ferrer-Correia, J. Madureira, Teresa M. Santos, Vitor Félix,