کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
9754989 | 1494897 | 2005 | 5 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
The potentiometric performances of cyclotetrahydroxysiloxane containing ferrocenyl moiety as an anion-selective membrane electrode
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کلمات کلیدی
موضوعات مرتبط
مهندسی و علوم پایه
شیمی
شیمی آنالیزی یا شیمی تجزیه
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چکیده انگلیسی
A test electrode based on cyclotetrasiloxane containing ferrocenyl, hydroxide and amine moiety exhibits very good potentiometric performance toward anions. Especially, acetate ion shows non-Hofmeister behavior on selectivity. The addition of the tetraalkylammonium salt provides lipophilic cationic sites within the membrane and enhances the response to more lipophilic anions. As expected, potentiometric performances of slopes and detection limits for the most of lipophilic anions, such as ClO4â and SCNâ, are the most enhanced. However, the response to acetate ion was significantly decreased. In our knowledge, this is the first report that cyclic siloxane containing functional groups such as ferrocenyl moiety and hydroxyl group shows possible usage as a neutral carrier for an anion sensor.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Microchemical Journal - Volume 80, Issue 2, June 2005, Pages 145-149
Journal: Microchemical Journal - Volume 80, Issue 2, June 2005, Pages 145-149
نویسندگان
Ki-Jung Paeng, Hyo Jin Jung, Se Jin Cho, Myong Euy Lee,