کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
9825421 | 1521788 | 2005 | 9 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
Separation of actinoids from HLW by thiacalix[4]arene compound impregnated silica ion-exchanger
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کلمات کلیدی
موضوعات مرتبط
مهندسی و علوم پایه
مهندسی انرژی
مهندسی انرژی و فناوری های برق
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چکیده انگلیسی
If trivalent actinoids such as Am can be separated from high-level radioactive liquid waste (HLLW) generated by the PUREX process, long-term heat and radiation hazards can be significantly reduced in the disposal of this waste. This paper reports the effective separation of Am through the use of a chelating ion-exchange method that uses an octylphenyl-N,N-diisobutylcarbomoyl phosphine oxide (CMPO) or thiacalix[4]arene compound impregnated silica ion-exchanger. The separation of Cs and Sr from HLLW can be achieved using a CMPO impregnated silica ion-exchanger (CMPO-exchanger). Actinoids and lanthanoids can then be eluted from the CMPO-exchanger, with the resulting solution then treated to separate the actinoids using a thiacalix[4]arene compound impregnated silica ion-exchanger. Thiacalix[4]arene compound impregnated silica ion-exchangers have been shown to effectively separate actinoids from lanthanoids in a weak-acid solution. The influence of gamma ray irradiation on adsorption is also investigated. The adsorption of Am remains high even after irradiation of the ion-exchanger.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Progress in Nuclear Energy - Volume 47, Issues 1â4, 2005, Pages 397-405
Journal: Progress in Nuclear Energy - Volume 47, Issues 1â4, 2005, Pages 397-405
نویسندگان
Takahiro Kikuchi, Ichiro Goto, Kazunori Suzuki,