Synthesis and characterization of mononuclear ruthenium complexes with carboxylato, chlorido and phosphine ligands. Crystal structures of [RuCl2{κ2-O,O-O2CCCH2(CH3)}(PPh3)2], [RuCl2(κ2-O,O-O2CC6H4-2-Cl)(PPh3)2], and [Et3NH][RuCl(SO2)(κ2-C,O-C6H4-2-CO2)
Keywords: کربوکسیلاتو; Ruthenium; Carboxylato; Cyclometallation; Synthesis; Crystal structure; Molecular orbital calculation;